Low-friction, oxidation-resistant, graphite and ceramic

CEVP's engineers have developed a range of low-friction, oxidation-resistant graphite and ceramic materials for use as bearings and seals in high temperature valve applications. This work has been predominantly for aerospace bleed and butterfly valves, operating at temperatures up to 700 C (in air).

The two main grades we use for the above applications are boronised graphite (grade BG10) and fine-grained hot isostatically pressed boron nitride (grade BN20). These offer the following advantages:

  • Very low oxidation rates up to 600 C/900 C in air (BG10/BN20 respectively)
  • Self lubricating
  • Low friction (hot or cold)
  • Good wear resistance
  • Excellent thermal shock resistance
  • High compressive strength
  • Light weight
  • Stable in damp or humid conditions
  • Good electrical conductor/insulator (BG10/BN20 respectively)
  • Good chemical stability

BG10 boronised graphite applications
The properties above make this material ideally suited to triple seals in hot air bleed valves, in aerospace applications. Triple seals made from BG10 very quickly polish the bore of the valve they are sealing, giving very low leakage rates. Once this initial polishing has taken place, very low wear rates to the seal and the valve bore are experienced during service. Application expoerience shows that leakage rates remain constant throughout the valve's service life, as the seal is hardly affected by oxidation or wear, and does not deteriorate.

This material also has a major advantage over conventional high temperature phosphate impregnated graphites, in that it is very stable in damp and humid conditions. Phosphate impregnated graphite's have been known to leach out the oxygen inhibiting phosphate (which can cause the valve to seize), if the valve becomes wet due to condensation or humidity.

BN20 boron nitride applications
This material has an extremely low friction coefficient and superb oxidation resistance, up to 900 C in air. It is ideally suited to bearing applications in hot air valves. It has a major advantage over metal bearings in that it exhibits low friction hot or cold -enabling smaller actuators to be used. High-temperature, self-lubricating metal bearings exhibit low friction when hot, but their friction increases dramatically when cold. This can give poor valve performance during start up, or necessitate a larger actuator to be used.

Specification of BG10 grade boronised graphite

Density

g/cm3

1.85

Hardness

Shore D

60

Flexural Strength

MPa

70

Compressive Strength

MPa

120

Modulus of Elasticity

GPa

20

CTE

10-6/°C

4.6

Max. operating temp.

In air

600°C


Specification of BN20 grade hot isostatically pressed boron nitride

Density

g/cm3

2.2

Flexural strength

MPa

32

Compressive strength

MPa

113

Young's Modulus

GPa

58

CTE

10-6/°C

8.0

Thermal conductivity @ 20°C

W/mK

49

Thermal conductivity @ 800°C

W/mK

28

Max. operating temp.

In Air

900°C

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